Iron speciation in natural waters by sequential injection analysis with a hexadentate 3-hydroxy-4-pyridinone chelator as chromogenic agent
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چکیده
منابع مشابه
Complexation of iron with the orally active decorporation drug L1 (3-hydroxy-1,2-dimethyl-4-pyridinone).
The stability constants for the Fe(III) complexes of the orally active iron decorporation drug L1 (3-hydroxy-1,2-dimethyl-4-pyridinone) have been determined by potentiometric titration [glass electrode, 25.0 degrees C, mu = 0.15 mol/L (isotonic) NaCl]. A simple computer model of blood plasma (citrate 100 mumol/L, transferrin 37 mumol/L) has been used to compare the Fe(III) binding efficacies in...
متن کاملSynthesis of New Bis(3-hydroxy-4-pyridinone) Ligands as Chelating Agents for Uranyl Complexation.
Five new bis(3-hydroxy-4-pyridinone) tetradentate chelators were synthesized in this study. The structures of these tetradentate chelators were characterized by ¹H-NMR, (13)C-NMR, FT-IR, UV-vis, and mass spectral analyses. The binding abilities of these tetradentate chelators for uranyl ion at pH 7.4 were also determined by UV spectrophotometry in aqueous media. Results showed that the efficien...
متن کاملDetermination of total iron as Fe(II) in multivitamins, haematinics and natural waters using a sequential injection (SIA) system
The determination of total iron in pharmaceutical products and natural waters as Fe(II) using a sequential injection system was investigated. A cadmium reductor consisting of cadmium granules was used to reduce Fe (III) to Fe (II). The Fe (II) was then determined (by its reaction with 1,10 Phenanthroline ) as a [Fe(phen)3 ] complex at 515 nm with a UV/Vis spectrophotometer. The linear range of ...
متن کامل3-Hydroxy-4-pyridinone derivatives as metal ion and amyloid binding agents.
Metal ions have been implicated in several neurodegenerative diseases, including Alzheimer's disease, as their dyshomeostasis may lead to production of reactive oxygen species as well as increased toxicity of amyloid protein aggregates. In this work, we present design and synthesis of three novel multifunctional hydroxypyridinone ligands, HL11, HL12, and HL13, bearing benzothiazole and benzoxaz...
متن کامل4-hydroxy-2-nonylquinoline: a novel iron chelator isolated from a bacterial cell membrane.
The membrane associated iron chelator of Pseudomonas aeruginosa has been extracted from membranes of iron-rich cells with ethanol and purified by reverse phase HPLC. Using 13C NMR and FAB mass spectroscopy, the structure of the chelator has been determined to be 4-hydroxy-2-nonylquinoline. This compound has been previously isolated and named pseudan IX, a name which we use here. We synthesized ...
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ژورنال
عنوان ژورنال: Talanta
سال: 2016
ISSN: 0039-9140
DOI: 10.1016/j.talanta.2015.05.062